Charge carrier kinetics and stability challenges in perovskite solar cells
James Durrant a b
a Department of Chemistry and Centre for Plastic Electronics, Imperial College London, South Kensington Campus, London, United Kingdom
b SPECIFIC, College of Engineering Swansea University, SPECIFIC, Baglan Bay Innovation Centre, Central Avenue, Baglan, Port Talbot, SA12 7AX, United Kingdom
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2017 (NFM17)
SF2 Solution Processed Innovative Solar Cells
Barcelona, Spain, 2017 September 4th - 9th
Organizers: Emilio Palomares and Garry Rumbles
Invited Speaker, James Durrant, presentation 184
Publication date: 20th June 2016

In my talk, I will focus primarily on the charge transfer and recombination processes which are key determinants of the efficiency of methylammonium lead halide perovskite solar cells. Experimentally our studies of charge transfer are based on transient absorption and photoluminescence measurements on timescales from femtoseconds to steady state. I will focus in particular upon the kinetics and efficiency of charge transfer from the photoactive perovskite layer to organic electron and hole collection layers in planar structure films and devices. Topics to be addressed will include the competition between charge transfer and charge trapping / recombination as a function of charge carrier density, material selection and processing and film aging, and the correlations between these processes and device photocurrent generation. The optical studies will be complimented by transient photocurrent and photovoltage studies of charge recombination as a function of photoactive layer and charge collection layer composition, and correlated with measurements of device voltage.

The second part of my talk will address the stability of the same devices, addressing in particular the photoinduced degradation of perovskite devices under oxygen exposure, and how the selection appropriate material choice and film processing can enhance performance.

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