Perovskite Quantum Dot Solar Cells—Stable Cubic CsPbI3 Films for High-Efficiency Photovoltaics
Joey Luther a
a NREL, 16253 Denver West Parkway, Golden, 80401, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2017 (NFM17)
SE1: Fundamental Processes in Semiconductor Nanocrystals
Barcelona, Spain, 2017 September 4th - 9th
Organizers: Arjan Houtepen and Zeger Hens
Invited Speaker, Joey Luther, presentation 181
Publication date: 20th June 2016

We demonstrate QD photovoltaic cells with an open-circuit voltage of 1.23 volts and power conversion efficiency of 13.4%. Despite very little research on this specific material system to date, the performance surpasses that of any other QD solar cell.  This new material system has incredible potential for many applications in optoelectronics, including multijunction photovoltaics, solid state lighting and display technology.  Here, I will present the basics behind the perovskite revolution over the past several years and a forward look into where this technology could make the greatest impact.

CsPbI3 is an all-inorganic analog to the hybrid organic cation halide perovskites, but the cubic phase of bulk CsPbI3 (a-CsPbI3)—the variant with desirable band gap—is only stable at high temperatures under conventional constructs. We describe the formation of α-CsPbI3 QD films through a colloidal quantum dot route that are phase-stable for months in ambient air. The films exhibit long-range electronic transport and are used to fabricate colloidal perovskite quantum dot solar cells. The modified size/phase stability will be discussed.

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