Proceedings of nanoGe September Meeting 2017 (NFM17)
Publication date: 20th June 2016
Studies of the preparation and properties of colloidal crystals comprised of nanocrystals (NCs) of controlled composition, size, shape, and surface functionalization provides insight into the fundamental organization of matter on multiple lengths scales. In this talk, we will share progress in the preparation of extended 3D periodic superlattice films and discuss the design rules that direct the formation of quasicrystalline systems. These NC assemblies offer novel platforms exploration of the cross coupling of physical properties as the quantum confined electronic states of semiconductor NCs interact with the plasmonic resonances of co-assembled noble metals and with nanomagnets, leading to hybrid properties on the mesoscale. To date, the programming of NC assemblies (extended lattices and discrete superparticles) has largely leveraged control of NC size and shape in combination with relatively simple surface functionalization by surfactants for close NC coupling and has leveraged DNA and polymers for larger NC spacings. The design of ligands and surface passivation can direct the organization and optimize the interaction between NCs and impart patchy/direction functionalization is of particular interest. We will share our efforts design surface ligands using a wider range of supermolecular chemistry and develop dendrimer-based stabilizers. These dendrimer / NC hybrids allow precise geometric and chemical control of the superlattice assembly symmetry and lattice spacing that govern NC interactions.