Proceedings of nanoGe September Meeting 2017 (NFM17)
Publication date: 20th June 2016
Solar chemical production attracts intense interest for converting solar energy into storable and distributable chemicals. While numerous semiconductors have been investigated, Si is among most promising semiconductors due to its bandgap of 1.12 eV. Here, I’ll present our recent works on Si photoelectrodes for efficient and selective photoelectrochemical (PEC) solar chemical production. Firstly, I’ll introduce a new PEC photoelectrode architecture which can maximize both light absorption and electrocatalysis on a photoelectrode. This architecture utilizes a high surface area, nanostructured cocatalysts locally defined on a photoelectrode. This local nanostructured cocatalysts provide large reaction sites and also allow light absorption in the photoelectrode. Along with PEC device modeling, we fabricate a model PEC device using Si photoanode with local Ni inverse opal (IO) nanostructures. By systematically changing surface coverage and surface area of Ni IOs on Si photoanodes, PEC devices physics of our photoelectrodes were investigated. In the second part of talk, I’ll talk about Si photocathodes with nanoporous Au cocatalysts for solar CO2 reduction reaction. The nanoporous Au cocatalysts is formed by simple electrochemical oxidation and reduction of Au thin films. Our Si photocathode with the nanoporous Au cocatalysts shows excellent CO2 reduction selectivity more than 90%. In the presentation, PEC performance of our Si electrode will be presented in detail.