Carbon Nitride Materials for Artificial Photosynthesis
Menny Shalom a
a Ben-Gurion University of the Negev, Israel, Beer-Sheva, Israel
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2017 (NFM17)
SE3: 2D Nanomaterials Synthesis and Applications
Barcelona, Spain, 2017 September 4th - 9th
Organizers: Hermenegildo García and Ana Primo
Invited Speaker, Menny Shalom, presentation 095
Publication date: 20th June 2016

One of the promising technologies for future alternative energy sources is the direct conversion of sunlight into chemical and electrical energy by using artificial photosynthesis. Artificial photosynthesis has attracted great interest over the last decades, especially for its potential to produce clean and cheap renewable energy without dependence on fossil fuels and without carbon dioxide emission. Artificial photosynthesis applications span from many fields such as: solar fuel production, water splitting, photo-degradation of pollutants, and catalysis of other chemical reactions, e.g. for the production of fine chemicals. An important challenge in artificial photosynthesis is the development of stable and inexpensive catalysts that can harvest the visible light in solar spectrum. Although the great progress in this field over the last years, the energy conversion efficiency of artificial photosynthesis remained low. Therefore, new approaches and new materials as photocatalysts and photoelectrocatalysts should be introduced for the improvements of artificial photosynthesis conversion efficiencies. While most of the research in this field is focused on metal based semiconductors (metal oxides, sulfides and nitrides) as photo (electro)catalysts, in the last years metal-free graphitic carbon nitride (g-CN) materials have attracted widespread attention due to their (electro)catalytic and photocatalytic activity alongside their low price and simple synthesis. In this talk I will show our recent progress in carbon nitride synthesis by using supramolecular chemistry to synthesize well-defined structures of g-CN such as hollow boxes, spheres, tubes and spherical macroscopic assemblies with the possibility to control their photophysical and photocatalytic properties. I will demonstrate in particular their operation as promising materials for artificial photosynthesis and other photoelectronic applications. I will introduce new approaches to grow g-CN layers with altered properties on conductive substrates for photoelectrochemical application. The growth mechanism of g-CN on flat and porous substrates as well as their chemical, photophysical, electronic and charge transfer properties will be discussed

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