Proceedings of nanoGe September Meeting 2017 (NFM17)
Publication date: 20th June 2016
Solution-processed materials have significant promise for future generation solar cells. We will discuss our efforts to understand charge transport and carrier lifetimes as a function of structure in two classes of materials for thin film solar cells.
Organic photovoltaics have a bulk heterojunction (BHJ) structure where an electron donor and acceptor meet in a bicontinuous network with nanoscale dimensions. The development of non-fullerene acceptors has led to prospects for improvement of their power conversion efficiency through reduced losses in the open circuit voltage. We will discuss recent work to understand the origin of these effects in non-fullerene acceptors through microstructural studies and device characterization.
Hybrid organic metal halides, such as CH3NH3PbI3, have garnered significant attention because they are earth-abundant, solution processable materials with high power conversion efficiency. The origin of the observed long carrier lifetimes in these materials that improve their electronic properties are still under significant debate. We will present our recent work on the properties of layered materials systems formed by replacement of halide ions by the pseudohalide thiocyanate (SCN-) and by the introduction of a mixed organic cations to form Ruddlesden-Popper structures. Using time-resolved microwave conductivity (TRMC), the carrier mobility of CH3NH3Pb(SCN)2I was found to be relatively high and comparable to that of polycrystalline CH3NH3PbI3 along with similar carrier lifetimes. In contrast, the layered R-P materials layered with organic cations do not show such apparent long lifetimes. We will present structural studies of polycrystalline thin films that help to address this difference in behavior.