Solar Water Photoelectrolysis with Hematite-based Photoanodes
Chunhua Cui a
a University of Zurich, Winterthurerstrasse, 190, Zürich, Switzerland
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Poster, Chunhua Cui, 076
Publication date: 14th June 2016

A great scientific and technological challenge facing humanity this century is the development of a clean, secure and sustainable energy source. H2 has been proposed as a major energy carrier for the future, and can be produced via a photosynthetic process from water. Today, however, H2 is produced mainly from steam reforming of natural gas, which contributes to CO2 emission. It is widely believed that the electrocatalytic process driven by photovoltage, namely photoelectrochemical (PEC) water splitting, will play a key role in next-generation technologies for sustainable-energy conversion, enabling clean hydrogen production.

Semiconductors and catalysts are essential components at the photoanode for PEC water oxidation. Semiconductors absorb solar light and generate electron-hole pairs; catalysts extract holes and catalyze water oxidation via a kinetically-slow four-electron process. The critical bottlenecks currently lie in improving the kinetics of electron transfer between the semiconductor and solution, decreasing the absorption of sunlight by the catalyst layer, and understanding interfacial energetics of the semiconductor/catalyst/solution system. The lack of success in the pursuit of efficient photoanode clearly indicates that new materials, chemistries and strategies are imperative. In this presentation, the focus will lie on the surface and interfacial engineering of semiconductor/catalyst/solution system.



© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info