Proceedings of September Meeting 2016 (NFM16)
Publication date: 14th June 2016
Sb based chalcogenides including Sb2Se3, CuSbS2 and CuSbSe2 represent a group of photovoltaic materials that are environmentally benign, relatively earth abundant and possessing attractive optoelectronic properties. In this presentation, the fundamental physical properties of these three compounds including their band gap, band position, defect chemistry, intrinsic and extrinsic doping and so on, will be first discussed as a rough evaluation for their potential as photovoltaic absorber materials. Then I will discuss hydrazine processed Sb2Se3, CuSbS2 and CuSbSe2 polycrystalline films and solar cells, and aqueous solution sprayed Sb2(S, Se)3 solar cells with special emphasis on the chemistry reaction involved in precusor dissolution and film formation. I will also briefly discuss vacuum processed Sb2Se3 solar cells with emphasis on the fabrication and characterization of the certified 5.6% device by rapid thermal evaporation. Key steps for device optimization, comparision between solution processing and vacuum processing, as well as perspective for the further optimization of Sb based chalcogenide solar cells will also be included in the talk.