Environmental Effects in Ultrafast Dynamics and Transport of 2D Nanostructures
Libai Huang a
a Purdue University, Department of Chemistry, 560 Oval Drive, West Lafayette, 47907, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Invited Speaker, Libai Huang, presentation 317
Publication date: 14th June 2016

I will present our recent work on transient absorption microscopy (TAM) as a new tool to image dynamics in 2D nanostructures with simultaneously high spatial (~ 200 nm) and temporal resolution (~ 200 fs) to investigate environmental effects in carrier dynamics and transport of 2D Nanostructures. I will discuss two examples of such transient absorption microscopic studies.  Femtosecond transient absorption microscopy was employed to study the environmental effects in carrier relaxation of graphene. We observed that the hot phonon effect occurs at much lower excitation intensity for suspended graphene compared to substrate-supported graphene.  The lifetime of the intrinsic optical phonons created by charge carrier relaxation is also longer for suspended graphene compared to substrate-supported graphene.  We attributed these observations to additional cooling channels provided by coupling between the charge carriers of graphene and the surface optical phonons of the substrate.  These results show the importance of the environment in controlling the carrier properties of graphene.Recent success in fabricating graphene has inspired researchers to search for semiconducting analogues of graphene in hopes to retain 2D crystallinity while providing a bandgap.  In particular, monolayer MoS2 has recently emerged as a promising candidate.  The second study I will present is the investigation of exciton dynamics in atomically thin and semiconducting MoS2 crystals.  By controlling the dielectric environment around monolayers of MoS2 crystals, our measurements provide a comprehensive understanding on intrinsic exciton dynamics, quantum confinement effect, exciton-phonon coupling, as well as how the dielectric environment alters optical properties and energy relaxation processes in these novel 2D crystals.  



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