Proceedings of September Meeting 2016 (NFM16)
Publication date: 14th June 2016
Having a theoretical 18.5% solar-to-hydrogen efficiency, LaTaON2 is anticipated to be an efficient photoanode material. However, LaTaON2 has been reported to exhibit very low solar photocurrent of 0.15 mA cm-2 at 1.6 VRHE in the literature. In this study, the solar photocurrent of LaTaON2 achieves a record value of 2.1 mA cm-2 at 1.6 VRHE, an order of magnitude higher than the previously-reported value. This dramatic enhancement is ascribed to hybrid structure of nanoparticles and porous microparticles, as well as CoOx modification. The hybrid structure may not only block the back reaction on the conductive substrates greatly, but also reduce the transfer distance of the photoinduced holes to reaction sites for water oxidation. On the other hand, the CoOx nanospheres, recrystallizing from the as-deposited amorphous layer after annealed under NH3, are observed by HRTEM (High Resolution Transmission Electron Microscopy). These CoOx nanospheres on LaTaON2 particles facilitate the formation of the Schottky nano-junctions accelerating the hole transport, thereby leading to ca. 260% increase in the photocurrent at 1.6 VRHE.