Liquid exfoliation of 2D materials: From scaleup to applications
Jonathan Coleman a
a Trinity College Dublin, College St, Dublin, 0, Ireland
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Invited Speaker, Jonathan Coleman, presentation 305
Publication date: 14th June 2016

In this talk I will describe liquid exfoliation of 2D materials. The simplest way to do this is to sonicate graphite in certain, stabilising solvents. When the solvent surface energy matches that of graphene the energetic cost of exfoliation is minimised and some of the graphite is converted to graphene. Graphite can also be exfoliated to give graphene by sonication in surfactants or polymer solutions. The resulting graphene is free of oxides and basal-plane defects and consists of nanosheets with lateral size of 200-2000 nm and thickness from 1-10 layers. This material can be used in arrange of applications, such as reinforced composites or strain sensors.This process can be extended to a host of other layered crystals including BN, MoS2, MoO3 and GaS. The exfoliation of MoS2 will be used as an example. In liquid exfoliation, it is important to know both the lateral size and thickness of the material being exfoliated. In the case of MoS2, we will show that this information is contained within the optical absorption spectrum. I will describe simple metrics which can be extracted from the MoS2 absorption spectrum and used to give the flake length and thickness directly. Access to such metrics allows the exfoliation process to be optimised to maximise monolayer content. As a result we can obtain monolayer-rich MoS2 dispersions which are photoluminescent. These methods can be applied to a range of 2D materials. To illustrate this, I will describe the production of MoTe2 dispersions which are monolayer-rich and photoluminescent.The availability of dispersions of a range of 2D materials allows the demonstration of a range of applications. We will demonstrate that liquid exfoliated nanosheets can be used to reinforce composites, replace Pt as the counter-electrode in dye-sensitised solar cells, act as catalysts to generate hydrogen, produce high capacitance supercaps and develop solution processed photodetectors.For any of the applications described above to be successful, a method of producing very large quantities of exfoliated nanosheets will be required. We have developed such a method in collaboration with Thomas Swan ltd. This method is based on high shear mixing. We have demonstrated the scalability of this method and envisaged the exfoliation mechanism. I will describe the production of batches of liquid exfoliated graphene with volumes of up to (but not limited to) 300 L.



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