Studies on the Stability of Photovoltaic Perovskite Materials and Devices: Thermal Assessment, Process, and Chlorine Incorporation
Joseph Luther a
a NREL, 16253 Denver West Parkway, Golden, 80401, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2015 (NFM15)
Santiago de Compostela, Spain, 2015 September 6th - 15th
Invited Speaker, Joseph Luther, presentation 234
Publication date: 8th June 2015

Hybrid organic/inorganic lead halide perovskite solar cells have already established themselves as an extremely promising PV technology despite only being investigated as such since 2009. Over the past few years, the sunlight-to-electricity conversion efficiency of these devices has improved dramatically from 3.8% to the current record of >20%, a rate unprecedented in the PV field. When this is considered in combination with the simple and inexpensive production process, it is easy to see why perovskites have generated a lot of excitement in the scientific community. While most devices mainly use I as the halogen, mixed halide perovskite precursors can be used to obtain CH3NH3PbI3-xClx. Results from these mixed halide perovskites has made it apparent that small changes in the composition and/or morphology of the crystalline perovskite layer can have dramatic effects on the overall performance of the PV device. The goal of this study was to develop a comprehensive, fundamental understanding of the crystallization process for triiodide perovskites as well as mixed halide perovskites. The formation of the crystalline layer was studied as a function of precursor composition and annealing conditions. Thermogravimetric analysis with differential scanning calorimetry (TGA-DSC), temperature-dependent X-ray diffraction (T-XRD), and temperature programmed decomposition mass spectrometry (TPD-MS) were all utilized to yield a more holistic picture. The new knowledge of this process will facilitate the future construction of highly efficient devices that can revolutionize the energy landscape. We have also explored the device functionality using scanning Kelvin probe microscopy to probe the operation mechanism as a function of film thickness. Furthermore, we will present stability data on the degradation of solar cells in a variety of aging conditions and thus provide insight into prolonging the lifetime as needed for commercialization of PV technology.  



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