Tracking process reproducibility of slot-die coated perovskite solar cells with systematic research data management
Eva Unger a b, Janardan Dagar a, Pramila Patil a, Arun Kumar a, Maja Tomic a, Anton Dzhong a, Lennart Klaus Reb a
a Helmholtz-Zentrum Berlin für Materialen und Energie GmbH, HySPRINT Innovation Lab, Kekuléstraße 5, 12489 Berlin, Germany
b Humboldt University Berlin, Department of Chemistry and CSMB, Zum Großen Windkanal 2, 12489 Berlin, Germany.
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges - #PerFut25
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Annalisa Bruno and Pablo P. Boix
Invited Speaker, Eva Unger, presentation 681
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.681
Publication date: 16th December 2024

Metal halide perovskites are at the forefront of next-generation optoelectronics due to their exceptional optoelectronic properties and ease of processing. However, challenges in scalability, stability, and process reproducibility remain critical barriers to their commercial adoption. In this work, we present the baseline we established for slot-die coated perovskite solar cells in the HySPRINT lab of HZB for small area test cells reaching up to 22% PCE collaboratively. We recently established a digital workflow collecting most relevant data regarding the fabrication of solar cells as well as their performance in the research data management platform NOMAD. We demonstrate how digital tools can greatly enhance intra-lab collaboration and will showcase how these kind of platforms can also be used for research data sharing by the wider research community.

We demonstrate the integration of in-situ process monitoring techniques, such as photoluminescence, during slot-die coating. These tools provide immediate feedback on critical parameters, including film thickness, drying kinetics, and phase evolution, enabling precise control over film quality and reproducibility. Data is complemented by in-situ process monitoring experiments using GIWAXS at the BESSY synchrotron.

Finally, we present an example of the fabrication of perovskite solar cell mini-modules using scalable methods, achieving efficiencies exceeding 20% with enhanced stability under operational conditions. The insights gained from these studies pave the way for the large-scale manufacturing of stable and efficient perovskite devices, addressing key technological challenges and supporting the field’s transition from laboratory to market.

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