Enhancing durability of automotive fuel cells via selective electrical conductivity induced by tungsten oxide layer coated directly on membrane electrode assembly
Sang-Hoon You a, Yong-Tae Kim a
a Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Electrochemical Water Treatment - #ELECTROWAT
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Julio J. Lado and Ignacio Sirés Sadornil
Poster, Sang-Hoon You, 582
Publication date: 16th December 2024

The poor durability, attributed to catalyst corrosion during start-up/shutdown (SU/SD), is a major obstacle to the commercialization of fuel cell electric vehicles (FCEVs). We recently achieved durability enhancement under SU/SD conditions by implementing a metal-insulator transition (MIT) using proton intercalation/deintercalation in WO3. However, such oxide-supported catalysts were unsuitable for direct application to the mass production stage of membrane electrode assembly (MEA) process due to their physical and chemical properties. Here, we report a unique approach that achieves the same durability enhancement in SU/SD situations while being directly applicable to the conventional MEA fabrication process. We coated WO3 on the bipolar plate, gas diffusion layer, and MEA to investigate whether the MIT phenomenon was realized. The WO3-coated MEA demonstrated 94% performance retention during SU/SD, the highest level to our knowledge. It can directly contribute to enhancing the durability of commercial FCEVs and be immediately applied to the MEA mass production process.

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