Highly stable perovskite-based x-ray detectors through the use of polymeric template
Silvia Colella a
a CNR-NANOTEC Istituto di Nanotecnologia, Via Orabona 4, 70125 Bari, Italy
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Emerging Radiation Detectors - #NextDetectors
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Miguel Anaya and Laura Basiricò
Invited Speaker, Silvia Colella, presentation 558
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.558
Publication date: 16th December 2024

Lead-Halide hybrid Perovskites are recently emerging as promising materials for high energy radiation detection thanks to the combination of high absorption coefficient, excellent transport properties, even in polycrystalline films, and their solution processability. Here we present Perovskite based X-ray detectors employing a perovskite-polymer composite thin film as active layer. The use of polymeric template for the perovskite growth allows a precise control of the active layer thickness and compactness, and confers to the device unconventional resistance to moisture and performances.[1] The performances of the active perovskite layer, inserted in a photodiode architecture, were studied under 40kV X-ray radiation. Remarkably, a top sensitivity of 5.5±0.2 μC Gy-1 cm-2 was measured for the device operating in passive mode (0V), coupled with exceptional stability. The samples were stored in air for 629 days tracking the performance degradation retaining 97% of the initial sensitivity. [2] A general overview of the potential of polymeric perovskite-based composites for x-ray detection in given.[3,4] 

References
[1] A Giuri, S Masi, A Listorti, G Gigli, S Colella, CE Corcione, A Rizzo, 'Polymeric rheology modifier allows single-step coating of perovskite ink for highly efficient and stable solar cells', 2018, Nano Energy 54, 400-408
[2] M. Verdi, A. Giuri, A. Ciavatti, A. Rizzo, L. Basiricò, S. Colella, B. Fraboni, 'Record stability for perovskite-based X-ray detectors through the use of polymeric template', under submission, 2023, Advanced Materials Interfaces 10 (18), 2300044.

[3] Incorporation of Functional Polymers into Metal Halide Perovskites thin-films: from interactions in solution to crystallization, 2023 Materials Advances.

[4] Implication of polymeric template agent on the formation process of hybrid halide perovskite films, Antonella Giuri, Rahim Munir, Andrea Listorti, Carola Esposito Corcione, Giuseppe Gigli, Aurora Rizzo, Aram Amassian, Silvia Colella, 2021, Nanotechnology.

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