Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.487
Publication date: 16th December 2024
Transition metal nitrides and oxynitrides were tested as electrochemical nitrogen reduction reaction (eNRR) catalysts for ammonia synthesis under ambient conditions. There have been several promising experiments on thin film electrodes in μ-reactor (Antec Scientific) (e.g.[1]). We have synthesized these catalysts as nanoparticles and incorporated to gas diffusion electrodes (GDE) to optimize the catalytic environment. One of the optimization steps needed is to understand the effect of pressure on the system. Gas pressure has been demonstrated to significantly affect the triple phase boundary and catalytic activity in CO2 reduction and is therefore anticipated also to have an effect in NRR [2], [3], [4], [5]. To increase the pressure in the flow cell and study the effect of the gas pressure on eNRR we have constructed a system for adjustable backpressure. To this end, a pressure-relief valve is used at the gas outlet of the flowcell. We will present studies focusing on the effect of the pressure increase on the catalytic behavior in a flow electrocell with gas diffusion electrodes for eNRR.
[1] F. Hanifpour, et al., Electrochimica Acta 2022, 403, 139551
[2] K. Hara et al., Journal of the Electrochemical Society 1995, 142, L57
[3] N. Sonoyama et al., Electrochemistry Communications 1999, 1, 213
[4] E.J. Dufek et al., Journal of The Electrochemical Society 2012, 159, F514
[5] B. Sahin, Energy Technology 2022, 10, 2200972
This work was supported by the Icelandic Fund for Technology Development [GA: 2321266-601, 2113091-0640], and the European Union, through project VERGE [HEU, GA: 101084253] Views and opinions expressed are however those of the author(s) only and do not necessarily reflect those of the European Union or the European Climate, Infrastructure and Environment Executive Agency. Neither the European Union nor the granting authority can be held responsible for them