Towards stable perovskite-silicon tandem solar cells: from nanometer- to wafer-scale
Christian Wolff a
a 1. École Polytechnique Fédérale de Lausanne (EPFL), IEM, PV-Lab, Rue de la Maladière 71b, 2000, Neuchâtel, Switzerland
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges - #PerFut25
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Annalisa Bruno and Pablo P. Boix
Invited Speaker, Christian Wolff, presentation 464
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.464
Publication date: 16th December 2024

Perovskite-silicon tandem solar cells are on the brink of commercialization, with efficiencies skyrocketing in the past 5 years, now being the most efficient two-terminal configuration ever made. Yet, the reliability of these devices is still a big question mark. This is in part due to the short time since their development hindering decade-long tests due to sheer time constraints, but also because there is a lack of established accelerated aging protocols due to a lack of understanding of primary failure modes. In the presentation, I will cover our recent results looking at the perovskite top cell and how nanometric defects (1) - how they trigger device degradation and how they can be mitigated – but also at effects on the um- and cm-scale, such as how the choice of the silicon cell texturing affects performance and stability (2), as well as long-distance ionic effects (3,4).

1. Othman et al., Adv. Mater. 2024, accepted
2. Turkay et al., submitted
3. Artuk et al., submitted
4. Jacobs et al., Energy Environ. Sci., 2022,15, 5324-5339

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