BL16 NOTOS: an X-ray absorption and diffraction beamline for operando battery studies at ALBA
Carlo Marini a, Carlos Escudero a, Eduardo Villalobos-Portillo a, Ilaria Lucentini a, Jordi Prat Albert a, Giovanni Agostini b
a ALBA Synchrotron Light Facility, Carrer de la Llum 2-26, 08290, Cerdanyola del Valles, Spain
b Sincrotrone Trieste, ELETTRA, 34012 Basovizza (TS), Italy
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
In situ/operando characterization of electrochemical energy materials with synchrotron X-ray techniques - #Operax
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Carlos Escudero and Juan Jesús Velasco Vélez
Invited Speaker, Carlo Marini, presentation 451
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.451
Publication date: 16th December 2024

Battery technology has become increasingly important in recent years due to the growing demand for portable electronic devices and electric vehicles, and to improve the performance and lifespan of batteries it is essential to understand the complex processes that occur during their operation. NOTOS is a beamline from ALBA Synchrotron Light Source devoted to X-ray Absorption Spectroscopy (XAS), X-Ray Diffraction (XRD) which has been designed to study the electronic structure and the short- and long-range order in a wide range of scientific disciplines: chemistry, catalysis/electrocatalysis, energy science, nanomaterials, condensed matter, and environmental science. The available energy range is now 4.5-30 keV and the photon source is a bending magnet, but it will be extended up to 35 keV thanks to a partial refurbishment of the optics and the change of the bending magnet with a SuperBend source in the framework of the ALBA-II upgrade. In addition to the capability to perform XAS and XRD investigations separately, the beamline allows quasi-simultaneous XAS-XRD experiments. Examples of XAS and XRD measurements on commercial electrodes (phospho-olivine LiFePO4 and NMC111) are presented showing the performances of the beamline in operando. Finally, as real research case, we discuss the structural stability of Bimetallic Cu-doped Gold Nanoclusters in electrochemical CO2 reduction. 

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