Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.425
Publication date: 16th December 2024
During the recent years, chiral hybrid organic-inorganic perovskites where the organic cations are the “source” of chirality, have received great attention from the physics and chemistry research community. Their functional properties enable the control of light, charge, and electron spins in the same materials. Here, we will discuss the intriguing “chirality transfer mechanism” in some newly synthesized ferromagnetic chiral hybrid inorganic perovskite along with their interplay with magnetism. Although the organic cations are chiral and polar molecules, their arrangement in the crystal structure results in a chiral non-polar space-group P212121. Moreover, we discuss a new chirality order parameter such as the electronic chirality measure (ECM) aiming at quantify the molecular cation chirality taking into account ionic and electronic degrees of freedom simultaneously. Also, the relation of ECM to physical properties of chiral hybrid perovskites will be discussed, so shedding light on the fundamental principles governing their behavior and paving the way for the development of innovative optoelectronic and spintronic devices.
No acknowledgments