Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.413
Publication date: 16th December 2024
The development of high-performing garnet based all-solid-state batteries requires intensive knowledge of the materials and processes throughout the whole cycle life of the battery to ensure ecological and economical battery production. Life-cycle analysis of the battery production line uncovered the production of raw materials and the temperature treatment steps as the crucial factors. Therefore, a better understanding of the garnet-based ceramic cathodes is needed.
3D analysis and reconstruction of the cells allowed the modelling of realistic microstructures and connects them to experimental data. This realistic cell model facilitates a deeper understanding of the limiting factors towards higher energy densities. Based on these findings, an optimized microstructure was derived. With the introduction of sequential tape-casting and an optimized sintering strategy to mitigate stresses in the material during high-temperature treatments, cathodes with this optimized microstructure were produced. These cathodes show a significant increase in the available areal specific capacity of ceramic batteries.
The introduction of advanced processing methods, as well as significant improvement of the anode side, an analysis of the degradation mechanisms in the cathodes during operation helped uncover the nature of capacity losses during cycling. Based on these findings, a strategy for direct recycling of the ceramic cells was derived, regaining over 40% of the initial capacity after complete degradation.