MAPbBr3-Ni(AcO)2 nanocomposite waveguides
Sandra Soriano Díaz a, Jaume Noguera Gómez a, Juan P. Martínez Pastor a, Pablo P. Boix a, Rafael Abargues a, Isaac Suárez a
a Instituto de Ciencia de los Materiales (ICMUV), Universitat de Valencia, 46980 Paterna, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Illuminating the Future: Advancements in Photon sources, Photodetectors, and Photonic Applications with 3D and low- dimensional metal halide perovskites - #PhotoPero
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Emmanuelle Deleporte, Blas Garrido and Juan P. Martínez Pastor
Invited Speaker, Isaac Suárez, presentation 343
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.343
Publication date: 16th December 2024

The solution processed semiconductors known as perovskites, or semiconductor perovskites (SP), has been widely studied as an idoneal platform to implement cost-effective integrated lasers.  From this perspective, there is an important concern on developing a SP technology to implement photonic integrated circuits. In this context, we have recently demonstrated that a nickel acetate, Ni(AcO)2, sol-gel is an exceptional and non-expensive matrix for SP nanocrystals. The distinctive advantage of this alternative technology relies on the in-situ crystallization of the perovskite nanocrystals during the spin-coating deposition, resulting on thin films with PL quantum yields exceeding 80 % and outstanding ambient and mechanical stability. This work successfully demonstrates the potential of Ni(AcO)2 containing MAPbBr3 (MA:methylamonium) SPs nanocrystals for active photonics. These nanocomposites are easily spin-coated on a SiO2/Si to conform planar waveguides. Moreover, the concentration of nanocrystal in the matrix allows the tunability of the optical properties, resulting in thin films with a tailor-made refractive index and absorption. Under optimal concentrations, the nanocrystals are homogeneously dispersed in the film and the waveguide efficiently propagates the light with relatively low losses. Here, the excitation beam injected in the structure gives rise to the generation of photoluminescence (PL) of the nanocrystals, and under certain excitation and propagation conditions, the generation of amplified spontaneous emission (ASE) and the formation of narrow random lasing (RL) under relatively small threshold (µJ/cm2). These results mark a significant step towards realizing the potential of perovskite nanocomposites in the field of optical waveguides.

This project received funding through projects no. PID2020-120484RB-I00, PID2019-107314RB-I00 (Stable) and PID2023-151632OB-C21 financed by the Spanish MCIN/AEI. This study also formed part of the Advanced Materials and Quantum Communication programs and was supported by MCIN with funding from European Union Next Generation EU (PRTR-C17.I1) within the project COMCUANTICA/009. SSD  and JNG acknowledge their FPU PhD contract with reference FPU22/00277 and FPU19/04544.

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