Halide Perovskite Nanocrystals: Synthesis, Growth Mechanisms, Superstructures, Heterostructures
Liberato Manna a
a Nanochemistry, Istituto Italiano di Tecnologia, 16163 Genova, Italy
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Advances in Nanocrystals: Fundamental approaches and technological perspectives - #NCAdv
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Carmelita Rodà and Matteo Zaffalon
Invited Speaker, Liberato Manna, presentation 336
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.336
Publication date: 16th December 2024

Halide perovskite semiconductors can merge the highly efficient operational principles of conventional inorganic semiconductors with the low‑temperature solution processability of emerging organic and hybrid materials, offering a promising route towards cheaply generating electricity as well as light. Following a surge of interest in this class of materials, research on colloidal halide perovskite nanocrystals (NCs) has gathered momentum in the last decade. This talk will highlight several findings of our group on their synthesis, for example our recent study on the influence of various exogenous cations and of acid-based equilibria on the growth of perovskite NCs, which can lead to the formation of NCs with peculiar shapes (for example hollow structures) and to NC heterostructures (for example CsPbBr3/PbS heterostructures) by promoting/suppressing the heterogenous nucleation of selected materials. I will also discuss our findings on the ordering of NCs in superstructures, and how cryogenic temperatures can influence the degree of ordering.

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