Glancing Angle Deposition of halide perovskites
Javier Castillo-Seoane a, Juan Delgado-Alvarez a, Lidia Contreras-Bernal a, Jose Manuel Obrero-Perez a, Xabier García-Casas a, Francisco Javier Aparicio a, Teresa Cristina Rojas a, Ana Borras a, Angel Barranco a, Juan Ramon Sanchez-Valencia a
a Institute of Materials Science of Seville, Spanish National Research Council – University of Seville, C. Américo Vespucio 49, Seville, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges - #PerFut25
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Annalisa Bruno and Pablo P. Boix
Oral, Juan Ramon Sanchez-Valencia, presentation 166
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.166
Publication date: 16th December 2024

Polarizers are ubiquitous components in modern optoelectronic devices  including displays and photographic cameras. However, achieving efficient control of light polarization remains an unsolved challenge. The main drawback of the existing display technologies relies on the substantial optical losses due to the use of polarizers for generating polarized light. In this context, organometal halide perovskite (OMHP) nanostructures offer a promising solution owing to their tunable optical properties—including adjustable bandgap, photoluminescence, and efficient light emission with minimal non-radiative recombination.[1–3] Their outstanding electrical properties have elevated hybrid perovskites as the material of choice in photovoltaics and optoelectronics. Among the different OMHP nanostructures, nanowires and nanorods have lately arisen as key players in controlling light polarization for lighting or detector applications.

In this work,[4] we propose applying an evolved version of the vacuum technique Glancing Angle Deposition (GLAD) as an advanced alternative to synthesising anisotropic-supported OMHP nanostructures. Our approach is a two-step fabrication procedure consisting of the room temperature deposition of PbI2 at glancing angles, followed by deposition of CH3NH3I at normal incidence (0º). As a result, highly anisotropic perovskite nanostructures resembling “nanowalls” have been fabricated. Such alignment degree endows the samples with anisotropic optical properties such as UV-visible absorption and photoluminescence. Moreover, their implementation in n-i-p solar cells can be used to develop self-powered polarization-sensitive photodetectors along the visible range. Thus, the use of Glancing Angle Deposition yields OMHP nanostructures with high anisotropy, controlled microstructure, and thickness, demonstrating potential for scalable, large-area fabrication. This technique is fully compatible with microelectronic and optoelectronic processing methods including CMOS and roll-to-roll technologies, which opens the path towards developing tuneable anisotropic optoelectronic devices based on OMHP.

Projects PID2022-143120OB-I00, TED2021-130916B-I00, and PCI2024-153451 funded by MCIN/AEI/10.13039/501100011033 and by "ERDF (FEDER), A way of making Europe”, Fondos NextgenerationEU and “Plan de Recuperación, Transformación y Resiliencia".

Project ANGSTROM was selected in the Joint Transnational Call 2023 of M-ERA.NET 3, which is an EU-funded network of about 49 funding organisations (Horizon 2020 grant agreement No 958174).

The project leading to this article has received funding from the EU H2020 program under grant agreement 851929 (ERC Starting Grant 3DScavengers).

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