Size Effects on Scintillation in Lead Halide Perovskite Nanocrystals
Andrea Fratelli a, Matteo L. Zaffalon a, Emanuele Mazzola b, Dmitry N. Dirin c, Ihor Cherniukh c, Clara Otero Martinez d, Matteo Salomoni b, Francesco Carulli a, Francesca Rossi e, Francesco Meinardi a, Luca Gironi b f, Liberato Manna d, Maksym V. Kovalenko c, Sergio Brovelli a f
a Dipartimento di Scienza dei Materiali, Università degli Studi di Milano-Bicocca, Via R. Cozzi 55, 20125 Milano, Italy
b Dipartimento di Fisica, Università degli Studi di Milano-Bicocca, Piazza della Scienza 3, 20126, Milano, Italy
c Department of Chemistry and Applied Biosciences, ETH Zürich, Zürich, Switzerland; Laboratory for Thin Films and Photovoltaics and Laboratory for Transport at Nanoscale Interfaces, Empa – Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, Switzerland
d Nanochemistry Department, Istituto Italiano di Tecnologia, Via Morego 30, Genova 16163, Italy
e IMEM-CNR, Parco Area delle Scienze 37/A, I-43124 Parma, Italy
f Istituto Nazionale di Fisica Nucleare (INFN), Sezione di Milano-Bicocca, Milan, Italy.
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Advances in Nanocrystals: Fundamental approaches and technological perspectives - #NCAdv
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Carmelita Rodà and Matteo Zaffalon
Oral, Andrea Fratelli, presentation 145
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.145
Publication date: 16th December 2024

The recent emergence of quantum confined nanomaterials in the field of radiation detection [1], in particular lead halide perovskite nanocrystals, offers scalability [2] and performance advantages [3] over conventional materials. This development raises fundamental questions about the mechanism of scintillation itself at the nanoscale and the role of particle size, arguably the most defining parameter of quantum dots. Understanding this is crucial for the design and optimisation of future nanotechnology scintillators.

In this work, we address these open questions by theoretically and experimentally studying the size-dependent scintillation of CsPbBr3 nanocrystals using a combination of Monte Carlo simulations, spectroscopic, and radiometric techniques. The results show that the simultaneous effects of size-dependent energy deposition, (multi-)exciton population, and light emission under ionizing excitation, typical of confined particles, combine to maximize the scintillation efficiency and time performance of larger nanocrystals due to greater stopping power and reduced Auger decay.

The agreement between theory and experiment produces a fully validated descriptive model that predicts the scintillation yield and kinetics of nanocrystals without free parameters, providing fundamental guiding for the rational design of nanoscale scintillators.

This work was funded by Horizon Europe EIC Pathfinder program through project 101098649 – UNICORN, by the PRIN program of the Italian Ministry of University and Research (IRONSIDE project), by the European Union—NextGenerationEU through the Italian Ministry of University and Research under PNRR—M4C2-I1.3 Project PE_00000019 “HEAL ITALIA”, by European Union’s Horizon 2020 Research and Innovation programme under Grant Agreement No 101004761 (AIDAINNOVA). This research is funded and supervised by the Italian Space Agency (Agenzia Spaziale Italiana, ASI) in the framework of the Research Day “Giornate della Ricerca Spaziale” initiative through the contract ASI N. 2023-4-U.0

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