MXene and hybrid electrodes for high performance energy storage
Volker Presser a b c
a INM - Leibniz Institute for New Materials, Campus D2 2, Saarbrücken, Germany
b Department Materials Science and Engineering, Saarland University, Germany, Germany
c saarene - Saarland Center for Energy Materials and Sustainability
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Nano Exploration of MXenes 2025 - #NEMX25
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Michelle Browne, Rui Gusmão and Bahareh Khezri
Invited Speaker, Volker Presser, presentation 037
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.037
Publication date: 16th December 2024

The field of battery research continually seeks to improve energy storage capabilities while addressing sustainability concerns. This applies in particular to the exploration and development of novel materials, such as the promising material group of MXenes. MXenes, known for their two-dimensional morphology, vast chemical composition range, and excellent electrical conductivity, require the synergistic integration of conversion or alloying materials to achieve high charge storage capacities.

The presentation highlights the development of high-performance sodium-ion batteries using MXene / antimony hybrid electrodes. By carefully optimizing synthesis parameters and material design strategies, researchers achieved an optimized electrode composition. This hybrid material exhibited a high reversible capacity of 450 mAh/g at 0.1 A/g, along with excellent cycling stability and rate capability. We also explore the combination of MXenes and SnO2, a conversion material, for enhanced lithium-ion battery performance of over 500 mAh/g for 700 cycles at 0.1 A/g. The researchers synthesized a nanocomposite consisting of a 50/50 mixture of SnO2 and MXene. The resulting nanocomposite demonstrated high-capacity retention over numerous cycles and excellent rate capability.

Additionally, we demonstrate MXene electrode recycling and upcycling. With binder- and additive-free MXene paper electrodes, we show the significance of finding sustainable and efficient approaches to recycle spent batteries. Researchers investigated the use of annealed delaminated MXene electrodes, obtained through vacuum-assisted filtration and annealing processes, in lithium-ion and sodium-ion batteries. The electrodes exhibited good electrochemical performance and were easily recovered through direct recycling processes, achieving high capacity recovery rates. Moreover, the cycled MXene electrodes could be transformed into TiO2/C hybrids with adjustable carbon content, providing opportunities for their utilization in various battery and electrocatalysis applications.

Collectively, we emphasize the potential of MXenes and MXene hybrid materials for enhancing charge storage capabilities in batteries. They also underline the significance of developing sustainable recycling and upcycling approaches for MXene electrodes, contributing to the overall advancement of battery technology.

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