Design of covalent triazine frameworks decorated with CuInS2 quantum dots of different sizes to boost photocatalytic hydrogen generation
Beata Bajorowicz a, Magdalena Miodyńska a, Tomasz Klimczuk b, Kostiantyn Nikiforow c
a Department of Environmental Technology, Faculty of Chemistry, University of Gdansk, Poland
b Department of Solid State Physics, Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Poland
c Mazovia Center for Surface Analysis, Institute of Physical Chemistry, Polish Academy of Science, Poland
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#NANOFUN - Functional Nanomaterials: from materials to applications.
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Emmanuel Lhuillier and Shalini Singh
Poster, Beata Bajorowicz, 346
Publication date: 28th August 2024

Photocatalysis, a technology that harnesses solar energy for the production of hydrogen via water splitting or the degradation of pollutants, is regarded as a promising strategy for addressing environmental issues in a sustainable manner. Among the various organic materials, covalent organic frameworks (COFs) have been identified as a promising candidate for photocatalysis due to their exceptional properties. These include tunability, crystallinity, stability, a large surface area and high porosity, and a low density [1]. Moreover, the integration of functional materials, such as quantum dots, with COFs represents a promising strategy for extending the absorption properties of these materials into the visible light region. This approach has the potential to enhance the photocatalytic performance of COFs by improving the separation and transfer of charge carriers [2].

This study presents the development of a novel class of porous organic frameworks-based photocatalysts by combining covalent triazine frameworks with CuInS2 quantum dots into a hybrid system via a post-modification approach. The influence of quantum dot size and amount on the optical, surface and photocatalytic properties of hybrid materials was investigated. Furthermore, the photoexcitation mechanism of covalent organic frameworks-based hybrids in the photocatalytic hydrogen production process was explored and proposed.

This research was funded by National Science Centre, Poland within the program OPUS 21, grant no. 2021/41/B/ST4/04393.

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