Chalcogenide thin film photovoltaics for indoor light harvesting
Robert Hoye a
a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, UK
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#ADINOS - Advances in inorganic thin film semiconductors for solar energy conversion
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Mirjana Dimitrievska and Sudhanshu Shukla
Invited Speaker, Robert Hoye, presentation 331
DOI: https://doi.org/10.29363/nanoge.matsusfall.2024.331
Publication date: 28th August 2024

The Internet of Things (IoT) is a rapidly growing ecosystem of billions of smart devices connected together via the cloud, embedding intelligence into infrastructure. But a significant challenge is the reliance of these devices on batteries as the power supply [1]. This talk explores the use of indoor photovoltaics (IPVs) as an alternative, either directly powering the IoT devices, or working in synergy with energy storage devices. Lead-halide perovskites currently demonstrate the highest power conversion efficiency (PCE), now approaching 45% [2]. However, the high lead content could act as a barrier to use in consumer electronics. This talk explores the development of IPVs from lead-free perovskite-inspired materials. We start with our early efforts on bismuth- and antimony-halide materials [3], discussing the challenges and opportunities with silver bismuth halide compounds [4], before covering our recent work with Sb2S3 IPV [5]. In the latter case, we achieve 17.55% PCE under indoor lighting, the highest yet reported for this material, and develop 5 cm2 minimodules as a prototype to power a multisensory device. We finish with the broader challenges and opportunities of the emerging area of perovskite-inspired materials for IPVs.

 

 

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