Understanding High Efficiencies in Perovskite LEDs
Neil Greenham a
a Cavendish Laboratory, University of Cambridge, Cambridge CB3 0HE, UK.
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#PeroLIGHT - Perovskites for Light Emission: From Materials to Devices
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Krishanu Dey, Sascha Feldmann and Xinyu Shen
Invited Speaker, Neil Greenham, presentation 150
DOI: https://doi.org/10.29363/nanoge.matsusfall.2024.150
Publication date: 28th August 2024

Use of additives to achieve careful control over perovskite morphology and interfaces can provide high-performance LEDs in the infrared and visible. I will discuss some recent examples where high efficiencies and high brightness can be obtained. Why, though, are efficiencies generally so high? Where extraction barriers are large, electron and hole injection must be well-balanced, and I will show how this is achieved through redistribution of the field across the two transport layers.  I will also show that light emission is rather uniform throughout the thickness of the devices despite the fact that electron and hole distributions are highly non-uniform.  Finally I will discuss optical outcoupling efficiency, highlighting the role of photon recycling where waveguided photons are absorbed and remitted, giving additional chances to escape. I will demonstrate a simple technique to enhance photon recycling by reducing parasitic optical absorption in the device, giving a significant boost to the overall device efficiency.

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