Microscopic Energy Carrier Transport in Nanocrystal Assemblies
James Utterback a
a Sorbonne Université, CNRS, Institut des NanoSciences de Paris, Place Jussieu, 4, Paris, France
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#NANOFUN - Functional Nanomaterials: from materials to applications.
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Emmanuel Lhuillier and Shalini Singh
Invited Speaker, James Utterback, presentation 148
DOI: https://doi.org/10.29363/nanoge.matsusfall.2024.148
Publication date: 28th August 2024

Optoelectronics applications require control over the generation, separation, and extraction of photoexcited charges and control over heat. Yet, in many material systems, energy carrier transport must navigate defects of various natures over a broad range of length and time scales. There are many approaches to inferring microscopic energy transport through energetic, temporal, or spatial markers, but each faces limitations. Moreover, heterogeneous systems are often elusive to simple kinetic models that reveal fundamental transport parameters. To understand the principles that govern electronic and thermal relaxation dynamics in complex systems relevant to optoelectronic applications, advanced experimental techniques and theoretical models rooted in fundamental physical phenomena are needed. This presentation will focus on the following questions: How do heterogeneous environments and interfaces impact microscopic energy transport? How can we access information about energy carriers that traditionally do not have clear spectroscopic signals? How can we control the directionality of energy carrier flow? I will describe pump–probe optical measurements and modeling of both charge-carrier and thermal transport in nanocrystal assemblies.

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