Selenium as a top-cell absorber for tandem photovoltaic- and PEC-cells
Peter Vesborg a, Rasmus Nielsen a, Thomas Youngman a, Alireza Azzar a, Andrea Crovetto a, Brian Seger a, Hadeel Moustafa a, Sergiu Levcenco b, Hannes Hempel b, Thomas Olsen a, Ole Hansen a, Ib Chorkendorff a, Thomas Unold b
a Technical University of Denmark (DTU), Denmark
b Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Berlin, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#ADINOS - Advances in inorganic thin film semiconductors for solar energy conversion
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Mirjana Dimitrievska and Sudhanshu Shukla
Invited Speaker, Peter Vesborg, presentation 143
DOI: https://doi.org/10.29363/nanoge.matsusfall.2024.143
Publication date: 28th August 2024

The ideal high-bandgap partner for a tandem solar absorber using c-Si as the low-bandgap bottom cell must have a bandgap of 1.6 eV to 1.9 eV and excellent optoelectronic properties.

Selenium, perhaps the very first material to be studied for its photovoltaic properties, is emerging as an interesting candidate for this application. Indeed Se has a bandgap of around 1.95 eV [1] and a steep increase in absorption above this photon energy. Todorov et al showed [2] in 2017 that single-junction Se solar cells could reach 6.5% efficiency using a new cell architecture with a very thin absorber layer. Recently we have increased the OCV to a new record of 991 mV [2] and mapped the main shortfalls of state-of-the-art Se-cells preventing them from approaching their theoretical potential OCV. The talk will introduce Se as a solar absorber and discuss we know about its properties and progress towards use in solar devices such as tandem photovoltaics and PEC stacks [3].

Independent Research Fund Denmark (DFF) Grant No. 0217-00333B

Villum Foundation V-SUSTAIN Grant No. 9455

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info