Publication date: 28th August 2024
Depleting reserves of fossil fuels and growing concerns with atmospheric CO2 levels necessitate the development of non-petroleum derived, renewable fuels and carbon-based building blocks for chemical industries. Solar and Biomass refineries have been proposed as potential replacements for the current petroleum paradigm, and one possible way to convert wate biomass to added value chemicals while also reducing water or CO2 to fuels is a direct photoelectrochemical approach. Identifying semiconductor material and co-catalyst combinations that can selectively drive key photo-oxidation reactions at high photocurrent densities remains a challenge in the field. In this presentation progress in developing semiconductors as photoanodes is discussed. Results with oxides like WO3, BiVO4, and SrTiO3 will be presented as well as with using 2D-TMD materials (MoS2) and organic semiconductor bulk heterojunctions. The oxidation activity toward key model reactions of the oxidation of biomass-derived 2,5-hydroxylmethylfurfural (HMF) into 2,5-Furandicarboxaldehyde (DFF) and 2,5-furandicarboxylicacid (FDCA), and the oxidation of glycerol will be examined and factors that determine selectivity will be presented. Aspects of solar light harvesting, material nanostructure, electrocatalysis kinetics, and charge-carrier separation/transport are discussed.