Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
DOI: https://doi.org/10.29363/nanoge.matsus.2024.389
Publication date: 18th December 2023
Organic-inorganic Pb halide perovskite (HaP)-based solar cells have shown great promise as a sustainable and economic way of electricity generation as its power conversion efficiencies skyrocketed to over 25% [1] within a decade of its introduction. To date, all the best-performing HaPs contain Pb and are fairly soluble in water. Pb is considered a hazardous heavy metal with major health concerns affirmed by various international organizations with recommended restricted levels of Pb in potable water (10-15 µg/L) [2]. One of the challenges of this technology is its potential environmental hazard of accidental Pb leached from broken cells/modules due to failure of encapsulation/packaging, vandalism, hail, storm, and subsequent rain. Quantifying the environmental hazard of accidental Pb2+ leaching, i.e., the reactivity and mobility of Pb2+ leached from HaP-based solar cells into the soil and from there to groundwater, was the goal of this research. Pb2+ originated from inorganic salts was previously found to remain in the upper soil layers due to adsorption. However, Pb-HaPs contain additional organic and inorganic cations, and competitive cation adsorption may affect Pb2+ retention in soils. We measured, analyzed and simulated the penetration depth profile of Pb2+ from HaPs and non-HaP sources into 3 types of agricultural soil under typical rain conditions, and its adsorption mechanism to the soil was described [2]. Most of the leached Pb2+ was found to be retained already in the first cm of the soil columns, and subsequent rain events do not induce Pb2+ penetration below the first few cm of soil surface irrespective of its sources and types of soil [3]. At conditions relevant to outdoor damage to HaP-based solar cells, it was found that the Pb2+ content retained by the topsoil is at least 100 times smaller than that of their maximum adsorption capacity. Surprisingly, organic co-cations from the dissolved HaP are found to enhance the Pb2+ adsorption capacity, compared to non-HaP-based Pb2+ sources. Our findings suggest that Pb2+ from damaged HaP-based solar cells is unlikely to contaminate groundwater, hence mass-scale utilization does not imply an environmental hazard. Panel installation over soil types with improved Pb2+ adsorption, regular inspection and removal of only the contaminated topsoil, are sufficient means to make the technology innocuous.
RDML and DC are grateful to the Israel Ministry of Energy for supporting our participation in the Solar ERAnet PERDRY project. RDML acknowledges funding from the European Union's Horizon 2020 MSCA Innovative Training Network under grant agreement no. 764787 and the EU MAESTRO project. This work was partially supported by the ISRAEL SCIENCE FOUNDATION (grant No. 1728/18). AM gratefully acknowledges the Israeli Planning and Budgeting Committee Fellowship for Outstanding Post-doctoral Researchers from China and India.