Electrolyte effects in electrocatalysis
Marc Koper a
a Leiden Institute of Chemistry, Leiden University
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#MatInter - Materials and Interfaces for emerging electrocatalytic reactions
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Marta Costa Figueiredo and María Escudero-Escribano
Invited Speaker, Marc Koper, presentation 334
DOI: https://doi.org/10.29363/nanoge.matsus.2024.334
Publication date: 18th December 2023

The electrocatalytic hydrogen and oxygen evolution reactions are the cornerstone reactions of water electrolysis. Here, I will discuss recent advances from my group in how the electrolyte composition determines the rate of these reactions. This complex interplay between electrode and electrolyte is currently still far from being completely understood. For the hydrogen evolution reaction (HER), cations play a key role in alkaline media in promoting or inhibiting the rate-determining step of HER. For the oxygen evolution reaction (OER) on NiFe-oxyhydroxide catalysts, cations have a strong effect on the non-kinetic contribution to the OER rate, suggesting that cations influence the accessibility of the active sites inside the layered oxyhydroxide. Finally, the electrolyte composition can have a major influence on bubble dynamics at high current densities, for both reactions. If time permits, I will also include examples on the effect of different electrolyte conditions on the electrocatalytic CO2 reduction in conjuction with local pH measurements.

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