Recycling and upcycling approaches to photovoltaics
Nripan Mathews a
a Nanyang Technological University, Nanomaterials Laboratory, S2.1-B5-01, School of Electrical & Electronic Engineering, NTU, Singapore, Singapore, Singapore
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#CircularMat - Circular Economy for Sustainable Energy Materials
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Susana Iglesias Porras, BENING TIRTA MUHAMMAD and Matthew Royle
Invited Speaker, Nripan Mathews, presentation 238
DOI: https://doi.org/10.29363/nanoge.matsus.2024.238
Publication date: 18th December 2023

The shift towards an energy mix with more renewable sources have resulted in massive quantities of solar photovoltaics being installed over the worls. This is a growing electronic waste stream that needs to be planned for. Present appropaches to solar recycling involve high-temperature burning for separation and release of the PV cells for metal recovery processes. However, such processes can release gaseous by-products that can cause serious health and environmental issues as well as deprioritises the recovery of pure silicon. This talk will cover our group's efforts in developing new extraction techniques that eschew burning as well as incorporate green solvents. Through an incorporation of such novel techniques along with hydrometallurgy, we demonstrate separation of glass, extraction of the various metallic elements such as Ag, Cu and Al as well as silicon at good purity levels. Our efforts in upcycling the extracted elements into other products such as thermoelectrics as well as battery anodes will also be described. 

This research is supported by the National Research Foundation, Singapore, and the National Environment Agency, Singapore under its Closing the Resource Loop Funding Initiative (Award No. CTRL-2023-1D-01).

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