Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
DOI: https://doi.org/10.29363/nanoge.matsus.2024.112
Publication date: 18th December 2023
The sun’s photons provide the largest source of energy on earth and its exploitation could help solve the energy crisis without being detrimental for the environment. Organic semiconductors, either polymers (usually electron donor) or small molecules (fullerene or non-fullerene acceptors), can be dispersed in water to provide human and environmentally-friendly processes for photovoltaics as alternative to classical options typically using toxic organic solvents. Concerning solar fuel production, Pinaud et al. have demonstrated by life cycle analysis that a colloidal system, in which the photocatalysts are in the form of nanoparticles dispersed in water, would be the cheapest technology to the production of H2.[1] Therefore there is an important need to study the formation of organic semiconducting nanoparticles and develop their use in these solar-technologies.[2]
In this communication, I will show what we have developed the 4 last years on this topic and more precisely the use of the Nanoprecipitation methodology to prepare the nanoparticles.[3] I will discuss its advantages and drawbacks and the Donnor/Acceptor morphologies that can be expected from nanoprecipitation. Through two systems, P3HT/PCBM and PTQ10/Y6 I will describe the incorporation of these dispersions as the medium for photocatalyzed hydrogen generation and as the active layer of photovoltaics cells.