Controlling Hysteresis Processes of Halide Perovskite for Solar Cell and Neuromorphic Applications
Juan Bisquert a
a Institute of Advanced Materials (INAM), Universitat Jaume I, Av. de Vicente Sos Baynat, s/n, 12006 Castelló, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#PerFut24 - The Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Annalisa Bruno, Iván Mora-Seró and Pablo P. Boix
Invited Speaker, Juan Bisquert, presentation 074
DOI: https://doi.org/10.29363/nanoge.matsus.2024.074
Publication date: 18th December 2023

The dynamic response of metal halide perovskite devices shows a variety of physical responses that need to be understood and classified for enhancing the performance and stability and for identifying physical behaviours that may lead to developing new applications. A multitude of chemical, biological, and material systems present an inductive behavior that is not electromagnetic in origin, termed a chemical inductor. We show that the structure of the chemical inductor consists of a two-dimensional system that couples a fast conduction mode and a slowing down element. The impedance spectra announce the type of hysteresis, either regular for capacitive response or inverted hysteresis for inductive response. We develop the methods to characterize time transient and photocurrent response to a voltage pulse. We can obtain important control of the time constant that determine hysteresis. We apply these insights in kinetics processes to the development of memristors and neurons. Overall we provide a method to determine important kinetic responses of the halide perovskites that can be aused in many different applications.

This work is funded by the project PID2022-141850OB-C21/AEI/10.13039/501100011033/FEDER, EU.

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