Proceedings of MATSUS23 & Sustainable Technology Forum València (STECH23) (MATSUS23)
DOI: https://doi.org/10.29363/nanoge.matsus.2023.065
Publication date: 22nd December 2022
Photovoltaic and solar fuels technologies rely upon the intentional movement of charge carriers (i.e. electrons and holes) and/or energy (i.e. excitons) in prescribed directions to convert sunlight into electricity or fuels. Two-dimensional semiconductors have several advantages for PV and (photo)catalytic technologies, due to their large absorption coefficients, high mobilities for charge carriers and excitons, and catalytic activity for important fuel-forming reactions. To realize the full potential of 2D nanomaterials and related heterostructures for sustainable energy technologies, fundamental studies are needed to probe the key photochemical processes that occur upon photon absorption, including exciton diffusion and dissociation, interfacial charge and energy transfer, and charge recombination. In this presentation, I will highlight our ongoing studies probing charge and energy transfer across heterojunctions formed between monolayer transition metal dichalcogenides (TMDCs) and other nanoscale semiconductors such as semiconducting single-walled carbon nanotubes, small molecules, and nanocrystals. Appropriate tuning of the interfacial band alignment can enable rapid exciton dissociation and exceptionally long-lived charge-separated states that are essential for PV and catalytic applications. Tuning the binding motif of molecular species between van der Waals association and covalent bonds can also influence the mechanisms of interfacial charge/energy transfer. If time permits, I will also discuss how certain 2D nanomaterials can facilitate charge/energy transfer while simultaneously blocking undesired ion movement across the heterojunction.