Charge and Energy Transfer Across Monolayer Semiconductor Heterojunctions
Jeff Blackburn a
a US National Renewable Energy Laboratory (NREL)
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS23 & Sustainable Technology Forum València (STECH23) (MATSUS23)
#2DSUSY - 2D Nanomaterials for Sustainable Energy
VALÈNCIA, Spain, 2023 March 6th - 10th
Organizers: Maria Antonia Herrero Chamorro and Maurizio Prato
Invited Speaker, Jeff Blackburn, presentation 065
DOI: https://doi.org/10.29363/nanoge.matsus.2023.065
Publication date: 22nd December 2022

Photovoltaic and solar fuels technologies rely upon the intentional movement of charge carriers (i.e. electrons and holes) and/or energy (i.e. excitons) in prescribed directions to convert sunlight into electricity or fuels. Two-dimensional semiconductors have several advantages for PV and (photo)catalytic technologies, due to their large absorption coefficients, high mobilities for charge carriers and excitons, and catalytic activity for important fuel-forming reactions. To realize the full potential of 2D nanomaterials and related heterostructures for sustainable energy technologies, fundamental studies are needed to probe the key photochemical processes that occur upon photon absorption, including exciton diffusion and dissociation, interfacial charge and energy transfer, and charge recombination. In this presentation, I will highlight our ongoing studies probing charge and energy transfer across heterojunctions formed between monolayer transition metal dichalcogenides (TMDCs) and other nanoscale semiconductors such as semiconducting single-walled carbon nanotubes, small molecules, and nanocrystals. Appropriate tuning of the interfacial band alignment can enable rapid exciton dissociation and exceptionally long-lived charge-separated states that are essential for PV and catalytic applications. Tuning the binding motif of molecular species between van der Waals association and covalent bonds can also influence the mechanisms of interfacial charge/energy transfer. If time permits, I will also discuss how certain 2D nanomaterials can facilitate charge/energy transfer while simultaneously blocking undesired ion movement across the heterojunction.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info