Vacuum deposited single junction and tandem perovskite solar cells
Henk Bolink a
a Instituto de Ciencia Molecular, ICMol, Universidad de Valencia
Proceedings of Asia-Pacific Conference on Perovskite, Organic Photovoltaics&Optoelectronics (IPEROP25)
Kyoto, Japan, 2025 January 19th - 21st
Organizers: Atsushi Wakamiya and Hideo Ohkita
Invited Speaker, Henk Bolink, presentation 017
Publication date: 4th October 2024

The benefits of vacuum processed perovskite solar cells will be discussed focusing on thermal co-sublimation but also using close-space sublimation methods. The performance of these cells under accelerated stress conditions and under outdoor stressing will be presented. Adding co-sublimation additives to the perovskite leads to improvements in performance and power conversion efficiencies around 20 % for perovskites with a bandgap around 1.68 eV can be achieved. Benefits of passivation molecules on the photoluminescence quantum yield and open circuit voltage will be described.

I will also discuss the benefit of using these perovskites in substrate configuration as well as semitransparent cells for bifacial operation and for building integrated PV. The use of sublimed perovskite in perovskite-silicon tandem cells using fully textured Si bottom cells will be presented, including methods to identify the shortcomings of these tandem cells such as selective Sun-Voc measurements allowing to identify the open circuit voltage of the perovskite and silicon sub cells and selective external quantum efficiency measurements.

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