Publication date: 4th October 2024
Semiconductor materials based on metal halide perovskites have attracted enormous attention in both research community and industry sectors in the past decade owing to their impressive performance demonstrated in the area of solar cells and other optoelectrical devices such as light emitting diodes, transistors etc. Currently the most widely used methods for synthesis of perovskite films is based on solution processing. The standard protocols of synthesis of the perovskite materials involves usage of large amount of hazardous, highly coordinating, aprotic polar solvent such as dimethylformamide (DMF) or carcinogenic N-methyl-2-pyrrolidone (NMP). The hazardous nature of these solvent raises concern for health, safety and environmental impact of these chemicals to humans and some of these solvent (e.g. DMF) has been banned to be used in manufacture in Europe. This restricts the commercial production of metal halide perovskite materials for various applications in practice.[1] Therefore it is highly critical to develop alternative sustainable solution processing for synthesis of metal halide perovskite using environmentally friendly, green solvent systems. In my talk, I will present our research on development of green processing methods for synthesis of metal halide perovskite using environmentally friendly solvent such as water, protic ionic liquids and biomass-derived solvent.[2] I will show that how the solvent system used in the material synthesis influence the physicochemical (morphology, optical and electrical) properties of the perovskite materials and the choice of precursor materials, which in turn determines the material’s performance in applications such as solar cells and light emitting diodes.