Correlation of charge carrier dynamics with the performance of metal halide perovskite solar cells
Yasuhiro Tachibana a b, Wakana Matsuda b
a RMIT University, Melbourne Victoria, Australia, Melbourne, Australia
b Osaka University, GSE Common East 1203, 2-1 Yamada-oka, Suita, Osaka, Japan
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP24)
Tokyo, Japan, 2024 January 21st - 23rd
Organizers: Qing Shen and James Ryan
Invited Speaker, Yasuhiro Tachibana, presentation 031
DOI: https://doi.org/10.29363/nanoge.iperop.2024.031
Publication date: 18th October 2023

Perovskite solar cells have been recognized as a newly emerging solar cell with the potential of achieving high efficiency with a low cost fabrication process. In particular, facile solution processed cell fabrication facilitated rapid development of optimum cell structure and composition. Over the last few years, the cell efficiency has reached 26%.

 

Highly efficient charge transfer reactions in addition to high charge separation efficiency and swift charge transport with minimum charge recombination are required to improve solar cell performance. Intensive studies  have been focused on monitoring photo-induced exciton formation and charge dissociation, charge transport and interfacial charge transfer dynamics including interfacial charge recombination in perovskite solar cells.[1-5] Several parameters have been identified to influence these charge carrier dynamics, and therefore the solar cell performance.[1-5] Clarifying these parameters is extremely important to understand the charge transfer mechanisms to further improve solar cell performance.

 

In this presentation, we will present parameters controlling charge dissociation in metal halide perovskites and their charge separation and recombination dynamics at the perovskite interfaces employing a series of transient absorption and emission spectroscopies. Correlation of the key parameters controlling the charge carrier dynamics with the solar cell performance will be discussed [1-5].

 

References

[1] S. Makuta, M. Liu, M. Endo, H. Nishimura, A. Wakamiya and Y. Tachibana, Chem. Commun., 52 (2016) 673 - 676.

[2] M. Liu, M. Endo, A. Shimazaki, A. Wakamiya and Y. Tachibana, J. Photopolym. Sci. Technol. 30 (2017) 577-582.

[3] M. Liu, M. Endo, A. Shimazaki, A. Wakamiya and Y. Tachibana, J. Photopolym. Sci. Technol., 31 (2018) 633-642.

[4] M. Liu, M. Endo, A. Shimazaki, A. Wakamiya and Y. Tachibana, ACS Appl. Energy Mater., 1 (2018) 3722-3732.

[5] M. Liu, H. Liu, S. R. Padmaperuma, M. Endo, A. Shimazaki, A. Wakamiya and Y. Tachibana, J. Photopolym. Sci. Technol., 32 (2019) 727-733.

This work was partly supported by JSPS KAKENHI Grant (19H02813) and (22H02182), and the Collaborative Research Program of Institute for Chemical Research, Kyoto University (grant number 2023-45 and 2022-99), Japan. We would like to acknowledge supports from the Australia-Japan Foundation for the international collaborative project. We also acknowledge supports from ARC LIEF fund (LE200100051 and LE170100235), Australia and School of Engineering in RMIT University, and Forefront Research Center, Faculty of Science at Osaka University.

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