MA-free Wide-Bandgap Perovskite for Indoor Photovoltaic Applications
Zhong-En Shi a, Chih-Ping Chen a
a Department of Materials Engineering, Ming Chi University of Technology, New Taipei City, Taiwan
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP24)
Tokyo, Japan, 2024 January 21st - 23rd
Organizers: Qing Shen and James Ryan
Oral, Zhong-En Shi, presentation 013
DOI: https://doi.org/10.29363/nanoge.iperop.2024.013
Publication date: 18th October 2023

Perovskite solar cells (PSCs) exhibit not only high efficiency under full AM1.5 sun-light, but also have great potential for applications in dim-light environments. Among the diverse family of ABX3 perovskites, methylammonium-free mixed halide CsxFA1–xPb(I1-yBry)3 perovskites appear as attractive light-absorber materials because of their optimum band gap, superior optoelectronic property, and good thermal stability. In this work, we demonstrated wide-band gap (WBG) perovskite photovoltaics with the composition of Cs0.18FA0.82Pb(I0.6Br0.4)3 yield high average PCEs of over 17% under AM1.5 sun-light and excellent performances under indoor light. Furthermore, we also fine-tuned the ratio and source of cesium ion to increases the grain size and film quality leading to improved charge mobility, reduced carrier recombination, and enhanced carrier lifetime, as confirmed by FESEM, XRD, PL and photo-CELIV and measurements. These findings showed the importance and potential of mixed cation, mixed-anion perovskite with tailored bandgap and suppressed trap-states in stable and efficient indoor light application.

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