Over 19% Efficiency in Ternary Organic Solar Cells Enabled by n-Type Dopants
Zhaoheng Ling a
a King Abdullah University of Science and Technology (KAUST), KAUST Solar Center (KSC), Thuwal 23955, Saudi Arabia
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP24)
Tokyo, Japan, 2024 January 21st - 23rd
Organizers: Qing Shen and James Ryan
Oral, Zhaoheng Ling, presentation 007
DOI: https://doi.org/10.29363/nanoge.iperop.2024.007
Publication date: 18th October 2023

The use of molecular dopants is an intriguing strategy for achieving a high power conversion efficiency (PCE) in organic solar cells (OSCs). However, despite its promise, the number of molecular dopants that enhance the PCE of OPVs remains limited. In this study, we introduce two novel n-type dopants, Ethyl Viologen (EV) and Methyl Viologen (MV), into ternary PM6:BTP-eC9-PC71BM bulk heterojunction (BHJ) OPVs and compare their performance with other known n-type dopants. Our findings reveal that the addition of EV and MV results in remarkable enhancements in PCE, reaching maximum values of 19.03% and 18.61%, respectively, along with fill factor (FF) values of 80% and 79.2%, respectively. We demonstrate that EV and MV function as both n-type dopants and microstructure modifiers, inducing enhancements in the absorption coefficient, balancing the charge carrier mobility, increasing the carrier lifetime, and reducing charge carrier recombination. Our results suggest that low concentrations of EV and MV can enhance the performance of highly efficient organic solar cells to levels beyond those achievable by the pristine BHJ.

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