Effective Passivation with Self-Organized Molecules for Perovskite Photovoltaics
Xinhui Luo a b, Hiroshi Segawa b c, Liyuan Han a b
a State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China.
b Special Division of Environmental and Energy Science, Komaba Organization for Educational Excellence (KOMEX), College of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro, Tokyo, 153-8902, Japan.
c Department of General Systems Studies, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP23)
Kobe, Japan, 2023 January 22nd - 24th
Organizers: Seigo Ito, Hideo Ohkita and Atsushi Wakamiya
Oral, Xinhui Luo, presentation 024
DOI: https://doi.org/10.29363/nanoge.iperop.2023.024
Publication date: 21st November 2022

Perovskite solar cells (PSCs) have achieved power conversion efficiencies (PCEs) exceeding 25% over the past decade. Effective passivation at the bottom interface with high trap density is challenging yet plays an important role in PSCs.[1,2] Here, organic molecules with A-D-A structure are studied as passivator. Firstly, we demonstrated that an advantageous molecular geometry and intermolecular ordering, aside from the functional moieties, are of great significance for effective and extensive passivation. Secondly, the passivation molecules spontaneously form a uniform passivation network adjacent to the bottom surface of perovskite films during a top-down crystallization via liquid medium annealing, which greatly reduces defect-assisted recombination throughout the whole perovskite/SnO2 interface. As a result, we achieved a device PCE over 25%.[1] Furthermore, we would like to extent the application field of the molecules in flexible PSCs. The investigation highlights a comprehensive understanding of designing passivation materials and provides a new avenue to achieve effective bottom-interface engineering for perovskite photovoltaics.

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