Publication date: 17th February 2025
Recently, the efficiency of p-i-n perovskite solar cells drastically increased, a pivotal factor being the incorporation of self-assembled monolayers (SAMs) as a hole-transporting layer (HTL). SAMs offer many advantages over conventional HTLs, including minimal material requirements, low cost, and facile processing. Current research is mainly focused on the development of carbazole-derived SAMs. However, the versatility of organic chemistry allows for the design of SAMs with alternative organic cores that may possess specific benefits. In this study, three novel SAMs are incorporated in p-i-n perovskite solar cells, each based on an aromatic core commonly used in organic semiconductors. The novel SAMs vary in their energy level alignment with the perovskite active layer. Optimal alignment is achieved with a pyrene-based SAM (4PAPyr), resulting in solar cells that outperform the commercially available 2PACz. Moreover, due to improved surface coverage, the use of 4PAPyr leads to a significantly higher number of working solar cell devices when compared to 2PACz, which is of particular interest with regard to upscaling. After device optimization, a power conversion efficiency of 22.2% is achieved with 4PAPyr. This research underlines the importance of diversifying SAMs to unlock further advancements in perovskite solar cell efficiency and scalability.
The authors thank the Research Foundation - Flanders (FWO Vlaanderen) for continuous financial support. S.Le, S.La, A.K., T.A., L.L., D.V., and W.T.M.V.G. thank the FWO for the funding of the FWO-SBO project PROCEED (S002019N). L.L., D.V., and W.T.M.V.G. are grateful to the FWO for the funding of the senior FWO research projects G043320N and G0A8723N. This study was supported by the special research fund (BOF) of Hasselt University (BOF21GP04) and The Energy Transition Fund (ETF) of Belgium (T-REX, 01/11/2021-31/10/2026).
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