Vitamins for stable non-fullerene organic solar cells
Vida Engmann a
a University of Southern Denmark, SDU CAPE
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV25)
Roma, Italy, 2025 May 12th - 14th
Organizers: Filippo De Angelis, Francesca Brunetti and Claudia Barolo
Invited Speaker Session, Vida Engmann, presentation 193
Publication date: 17th February 2025

Organic solar cells have recently broke the power conversion efficiencies limit of 20%. This puts extra attention to increasing their stability as their last remaining weak point. Since they consist of organic molecules, they are susceptible to oxygen, light, heat and humidity, which are commonly found stresses in their working environment.

 

Different tabilizing additives (antioxidants, radical scavengers, hydroperoxide decomposers, UV absorbers) can be incorporated in active layers of organic solar cells to inhibit degradation. This is both inexpensive and easily upscalable, and it does not introduce further complexity into the device architecture.

Here we will present our recent results on long-term stability improvement using naturally occurring antioxidants that act as singlet oxygen quenchers and radical scavenging compounds in highly efficient non-fullerene based organic solar cells.

 

references:

1. Atajanov R, Turkovic V et al.  The mechanisms of degradation and stabilization of high-performing non-fullerene acceptor based organic solar cells. (in preparation)

 

2. Balasubramanian S, Turkovic V et al. Vitamin C for Photo-Stable Non-fullerene-acceptor-Based Organic Solar Cells. ACS Appl Mater Interfaces 2021; dx.doi.org/10.1021/acsami.3c06321

 

3. Prete M, Turkovic V et al. Synergistic effect of carotenoid and silicone-based additives for photooxidatively stable organic solar cells with enhanced elasticity. J Mater Chem C 2021; dx.doi.org/10.1039/D1TC01544C

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