Interfacial Engineering of Lead-based and Lead-free Perovskite Solar Cells
Tsutomu Miyasaka a
a Toin University of Yokohama, 1614 Kurogane-cho, Aoba, Yokohama, 2258503, Japan
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV25)
Roma, Italy, 2025 May 12th - 14th
Organizers: Filippo De Angelis, Francesca Brunetti and Claudia Barolo
Keynote, Tsutomu Miyasaka, presentation 134
Publication date: 17th February 2025

The current R&Ds of perovskite solar cells (PSCs) has created many unique methods in molecular engineering, using organic molecules, for defect passivation at grain boundaries and heterojunction interfaces in PSCs.1 Our group has focused on the method of interfacial passivation with functional organic molecules, which enables high voltage output (close to theoretical limit) in photovoltaic performance.2 For practical applications, the stability of the devices still remains a major challenge. Organic cations in halide perovskites and diffusible dopants in hole transport materials (HTMs) are responsible for low stability at high temperatures (>120oC). To solve this, all-inorganic compositions of perovskite and use of dopant-free HTMs are highly desired. CsPbI2Br PSCs (bandgap 1.9eV) achieved high Voc over 1.4V with PCEs of >17%. Under indoor LED illumination, it works at PCE >34% being supported by high Voc.3 Passivation of iodine defects with 2,5-thiophenedicarboxylic acid (TDCA) achieved Voc of 1.54V for CsPbIB2.4 As inorganic perovskites, lead-free compositions such as Ag-Bi halides also become an important target for achieving environmentally kind PSCs.5 AgBiS2 as a sulfur-based IR-absorbing material achieves high photocurrent densities (>34mA/cm2).6

For implementation of PCSs in society, lightweight modules are demanded. Thin plastic film-based PCSs are manufactured by low-temperature material preparation.7 Ink-jet coating process is applicable for device fabrication. This topic will also be introduced in the lecture.

 

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