Molecular engineering of photochromic dyes for DSSCs with improved performance
Diego Mirani a, Samuel Fauvel a, Jhon-Edinson Galvez Arango a, Pascale Maldivi a, Antonio J. Riquelme a, Cyril Aumaitre a, Renaud Demadrille a
a Univ. Grenoble Alpes, CEA, CNRS, IRIG-SyMMES, 38000 Grenoble, France.
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV25)
Roma, Italy, 2025 May 12th - 14th
Organizers: Filippo De Angelis, Francesca Brunetti and Claudia Barolo
Oral, Diego Mirani, presentation 101
Publication date: 17th February 2025

Photovoltaic energy sources have emerged as a viable alternative to meet the world’s growing energy needs. However, current commercial technologies, such as silicon-based solar cells, require energy-intensive manufacturing processes, resulting in longer Energy Payback Time.[1] Among other emerging photovoltaic technologies,[2] Dye-Sensitized Solar Cells (DSSCs) stand out for their promising properties, including low-cost fabrication, easy tunability of absorption properties to produce solar cells in different colours, and high stability.[3,4]

Given the possibility of working with transparent substrates with DSSCs, the idea of using them as smart windows has driven research into dyes with a wide range of colours and on the implementation of photochromic dyes to obtain devices with self-regulating coloration.[5,6] To this end, different families of photochromic dyes based on diphenyl-naphthopyran moiety have been intensively studied, with efficiencies above 4% and fast coloration/discoloration kinetics.[7]

The fast response time and strong fatigue resistance of naphthopyran-based photochromic dyes make them highly valuable for various optical and smart applications. A key feature of these molecules is their tunability: by exploiting advances in organic dye research, modifications can be made to their donor, acceptor, or pi-conjugated systems. These adjustments allow precise control of their optoelectronic properties, leading to improved solar cell efficiencies and optical performance.

In this work, we will present new structures of photochromic dyes for dye-sensitised solar cells by implementing different donor or acceptor units. We will discuss the theoretical investigation carried out by DFT calculations, the synthesis of the dyes and their characterisation, and finally their implementation in devices and their characterisation to determine their photovoltaic properties. We will show that these new dyes can be used to develop solar cells with panchromatic absorption and high colour rendering index, opening up new applications in glazing.

This project has received funding under the European Union’s Horizon 2020 research and innovation program (grant agreement number 832606; project PISCO).

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