(Online talk) Coupled vibrational modes in organic crystals
Omer Yaffe a
a Weizmann Institute of Science, Herzl St. 234, Rehovot 7610001, Israel
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
València, Spain, 2024 May 12th - 15th
Organizer: Bruno Ehrler
Invited Speaker Session, Omer Yaffe, presentation 147
DOI: https://doi.org/10.29363/nanoge.hopv.2024.147
Publication date: 6th February 2024

The phenomenon of mode coupling holds significance across various domains of solid-state physics. In the context of organic crystals, understanding the implications of coupled lattice modes is crucial for unraveling the mechanisms behind phase transformations and electron-phonon interactions. In my talk, I will explore how the coupling between vibrational modes is evident in inelastic light scattering. Through experimental case studies, I will illustrate how employing mode coupling models in analyzing Raman spectra enables us to shed light on critical phenomena, such as how a phase transition arises from the thermal population of vibrational states.

In the initial segment of my talk, I will demonstrate that the polarization dependence of Raman scattering in organic crystals at finite temperatures necessitates a description through a fourth-rank tensor formalism. This expansion beyond the conventional second-rank Raman tensor is represented by off-diagonal components in the crystal self-energy on the light scattering process. In the latter part, I will discuss the temperature-dependent evolution of vibrational modes in α α-glycine crystals. Despite its straightforward structure and the absence of known phase transitions, I will present evidence of a phase transition manifesting within the vibrational modes closely associated with the potential surface of its hydrogen bonds.

 

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