Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
DOI: https://doi.org/10.29363/nanoge.hopv.2024.108
Publication date: 6th February 2024
Will Vapor Phase Deposition of Perovskite Photovoltaics Accelerate Commercialization?
Ulrich W. Paetzold* 1,2
Karlsruhe Institute of Technology, Institute of Microstructure Technology Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen Germany
Karlsruhe Institute of Technology, Light Technology Institute Engesserstrasse 13, 76131 Karlsruhe, Germany
Mail: Ulrich.Paetzold@kit.edu
Vapor phase deposition of organic-inorganic perovskite solar cells (PSCs) is raising increasing interest in academia and industry, holding great promise for commercializing perovskite-based photovoltaics (PV). Despite the well-established use of vapor phase deposition processes in commercial manufacturing of thin-film photovoltaics and other optoelectronic applications, research on vapor phase processed PSCs is still underrepresented compared to their solution-based counterparts. Solution-processed PSCs still dominate the academic research, benefiting from fast optimization feedback and straightforward integration in modern research laboratories.
This contribution will present a recently published perspective (Ref 1) by an international team that conveys a balanced viewpoint from industry and academics on the prospects for vapor phase deposition of perovskite-based PV. The perspective highlights strategic opportunities of vapor phase deposition for the its commercialization of perovskite-based PV. In addition, the latest developments at the Karlsruhe Institute of Technology on vapor phase deposited PSCs and perovskite/Si tandem solar cells will be presented. With regard to co-evaporated PSCs, we have recently developed a comprehensive understanding of how interfacial hydrogen bonding impacts bulk perovskite properties, highlighting the potential for rational design of substrates to control organic cation incorporation (Ref. 2), and enabling us to incorporate our evaporated self-assembled monolayer hole transport layers (Ref. 3) into all-evaporated PSCs. In addition, our recent progress on sequentially evaporated and hybrid-processed PSCs will be summarized at the conference.
(1) Vapor Phase Deposition of Perovskite Photovoltaics: Short Track to Commercialization?
T. Abzieher, D. More, …, and U.W. Paetzold.
Energy & Environmental Science 2024 (DOI: 10.1039/D3EE03273F)
(2) Understanding and exploiting interfacial interactions between phosphonic acid functional groups and co-evaporated perovskites
T. Feeney, J. Petry, …, and U.W. Paetzold.
Matter 2024 – Accepted not published.
(3) Evaporated Self-Assembled Monolayer Hole Transport Layers: Lossless Interfaces in p-i-n Perovskite Solar Cells
A. Farag, T. Feeney, …, and U.W. Paetzold.
Advanced Energy Materials 13(8), 2203982 2024 (DOI: 10.1002/aenm.202203982)
The author acknowledges the contributions of all colleagues contributing to this presentation, i.e., T. Abzieher, D. More, P. Fassl, T. Feeney, J. Petry, A. Diercks, and many more. The financial support by the Federal Ministry for Economic Affairs and Climate Action of Germany under grant agreement 03EE1123A (project SHAPE) and 03EE1056B (27Plus6) as well as the European Union through HORIZON EUROPE Research and Innovation Actions under grant agreement number 101075330 (project NEXUS) is highly appreciated. Views and opinions expressed are those of the authors only and do not necessarily reflect those of the European Union or the European Climate, Infrastructure and Environment Executive Agency (CINEA). Neither the European Union nor the granting authority can be held responsible.
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