Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
DOI: https://doi.org/10.29363/nanoge.hopv.2024.006
Publication date: 6th February 2024
Since the pioneer work of Brian O’Regan and Michael Grätzel in 1991, dye-sensitized solar cells (DSSC) have attracted many attentions for their ease of fabrication, their performances and their stability. Despite efficiencies above 15% nowadays, DSSCs are not yet able to compete with more mature technologies such as silicon solar cells (efficiency around 20%). However, DSSCs are displaying unique advantages such as semi-transparency, high efficiency under low-light intensity and a pleasing aesthetic making them highly attractive for indoor application or building integrated photovoltaic.
The development of photochromic DSSCs, which can self-adapt their light transmission to the intensity of the ambient light, could be crucial for developing BIPV. We focus on the previously reported diphenyl-naphthopyran series [1], analyzing their optoelectronic behavior by adapting small-perturbation techniques to the inherent properties of the photochromic dye to unravel the electronic processes at the electrode-dye-electrolyte interfaces[2]. We use molecular engineering to develop different series of naphthopyran dyes with an identical pi-conjugated backbone and varying alkyl substituents reported to control the discoloration kinetics and reduce the recombination processes, achieving power conversion efficiencies of over 4.3% [3]. We also report a new family of photochromic dyes introducing a diphenylamine-type donor moiety and functionalized carbazoles, to tune their optical properties to match the photopic response of the human eyes[4].