Insights from Optoelectronic Small Perturbation Techniques on Photovoltaic Process in Photochromic Dye-Sensitized Solar Cells
Antonio J. Riquelme a, Valid M. Mwalukuku a, Samuel Fauvel a, Johan Liotier a, Yann Kervella a, Quentin Huaulmé a, Alix Haurez a, José-María Andrés-Castán a, Stéphanie Narbey b, Juan A. Anta c, Renaud Demadrille a
a Univ. Grenoble Alpes, CEA, CNRS, IRIG-SyMMES, 17 rue des Martyrs, 38000 Grenoble, France
b Solaronix SA, Rue de l’Ouriette 129, Aubonne, 1170, Switzerland
c Area de Química Física, Departamento de Sistemas Físicos, Químicos y Naturales, Universidad Pablo de Olavide, Sevilla, Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
València, Spain, 2024 May 12th - 15th
Organizer: Bruno Ehrler
Oral, Antonio J. Riquelme, presentation 006
DOI: https://doi.org/10.29363/nanoge.hopv.2024.006
Publication date: 6th February 2024

Since the pioneer work of Brian O’Regan and Michael Grätzel in 1991, dye-sensitized solar cells (DSSC) have attracted many attentions for their ease of fabrication, their performances and their stability. Despite efficiencies above 15% nowadays, DSSCs are not yet able to compete with more mature technologies such as silicon solar cells (efficiency around 20%). However, DSSCs are displaying unique advantages such as semi-transparency, high efficiency under low-light intensity and a pleasing aesthetic making them highly attractive for indoor application or building integrated photovoltaic.

The development of photochromic DSSCs, which can self-adapt their light transmission to the intensity of the ambient light, could be crucial for developing BIPV. We focus on the previously reported diphenyl-naphthopyran series [1], analyzing their optoelectronic behavior by adapting small-perturbation techniques to the inherent properties of the photochromic dye to unravel the electronic processes at the electrode-dye-electrolyte interfaces[2]. We use molecular engineering to develop different series of naphthopyran dyes with an identical pi-conjugated backbone and varying alkyl substituents reported to control the discoloration kinetics and reduce the recombination processes, achieving power conversion efficiencies of over 4.3% [3]. We also report a new family of photochromic dyes introducing a diphenylamine-type donor moiety and functionalized carbazoles, to tune their optical properties to match the photopic response of the human eyes[4].

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info